Mars 2021.

Publication des équipes S2OMaF et SCL du laboratoire Moltech-Anjou dans RSC Advances

 

Synthesis and self-assembly of a penta[60]fullerene bearing benzo[ghi]perylenetriimide units

ABSTRACT: A benzo[ghi]perylenetriimide (BPTI) derivative bearing a terminal azido group on the expanded π-conjugated backbone has been synthesized and characterized. This promising photo- and electroactive BPTI motif has been used to obtain an original penta(organo)fullerene as a promising multi-electron acceptor system. Our studies show its self-assembly resulting from aggregation via π–π stacking interaction in solution and in the solid state. 
 
 
 
DOI: doi.org/10.1039/D1RA00287B