Publication Électrochimie - J. Electroanal. Chem, nov. 2022

The November 15, 2022

Nouvel article d'électrochimie du laboratoire MOLTECH-Anjou dans Journal of Electroanalytical Chemistry :

Use of phase angle in alternating voltammetry on redox self-assembled monolayers with intermolecular interactions.

Olivier Alévêque and Eric Levillain

Abstract

We present a methodology based on the study of the frequency dependence of the phase angle in Alternative Voltammetry to estimate the standard electrochemical rate constant for heterogeneous electron transfer reactions in the case of strong intermolecular interactions occur between the redox forms. This work is a follow-up to our previous study which was dedicated only to the study of peak currents.

DOI: 10.1016/j.jelechem.2022.116914