Publication PulSAr - Org. Biomol. Chem., jan. 2022

The January 6, 2022

Nouvel article de revue de l'équipe PulSAr dans Organic & Biomolecular Chemistry:

An investigation of palladium-catalyzed Stille-type cross-coupling of nitroarenes in perylenediimide series.

Aline Makhloutah, Danylo Hatych, Thomas Chartier, Lou Rocard, Antoine Goujon, François-Xavier Felpin and Piétrick Hudhomme

Abstract

We report herein an unprecedented palladium-catalyzed cross-coupling reaction between mononitro-perylenediimide (PDI) and various arylstannanes. Optimized conditions developed with this Stille-type reaction allow the grafting of (hetero)aryls of various electronic nature in the bay region of PDIs. Moreover, we capitalized on the high selectivity of this cross-coupling through the desymmetrization of the dinitro-PDI substrate.

DOI: 10.1039/D1OB02291A