Publications

2023

Chirality Versus Symmetry: Electron’s Spin Selectivity in Nonpolar Chiral Lead-Bromide Perovskites.
A. Abhervé, N. Mercier, A. Kumar, T. K. Das, J. Even, C. Katan, M. Kepenekian, Adv. Mater. 2023, 2305784.

https://doi.org/10.1002/adma.202305784 

Halide Containing Short Organic Monocations in n = 1–4 2D Multilayered Halide Perovskite Thin Films and Crystals.
A. Skorokhod, C. Quarti, A. Abhervé, M. Allain, J. Even, C. Katan, N. Mercier, Chem. Mater. 2023, 35, 2873.

https://doi.org/10.3390/cryst12060763

2022

Metal-Organic Framework vs. Coordination Polymer—Influence of the Lanthanide on the Nature of the Heteroleptic Anilate/Terephtalate 3D Network.
M. Oggianu, F. Manna, S. Ashoka Sahadevan, N. Avarvari, A. Abhervé, M. L. Mercuri, Crystals 2022, 12, 763.
https://doi.org/10.3390/cryst12060763

Chiral Emissive Lanthanide Complexes from Enantiopure [6]Helicene-bis(pyrazolyl)-pyridine Ligands.
A. Abhervé, M. Mastropasqua Talamo, N. Vanthuyne, F. Zinna, L. Di Bari, M. Grasser, B. Le Guennic, N. Avarvari, Eur. J. Inorg. Chem. 2022, e202200010.
https://doi.org/10.1002/ejic.202200010

Enhancement of electrocatalytic oxygen evolution by chiral molecular functionalization of hybrid 2D electrodes.
Y. Liang, K. Banjac, K. Martin, N. Zigon, S. Lee, N. Vanthuyne, F. A. Garcés-Pineda, J. R. Galán-Mascarós, X. Hu, N. Avarvari, M. Lingenfelder, Nat. Commun. 2022, 13, 3356.
https://doi.org/10.1038/s41467-022-31096-8

[4]Helicene-based anions in electrocrystallization with tetrachalcogeno-fulvalene donors.
N. Zigon, N. Avarvari, CrystEngComm 2022, 24, 1942–1947.
https://doi.org/10.1039/D2CE00091A

Chiral Bis(tetrathiafulvalene)-1,2-Cyclohexane-diamides.
A. Bogdan, I.-T. Moraru, P. Auban-Senzier, I. Grosu, F. Pop, N. Avarvari, Molecules 2022, 27, 6926.
https://doi.org/10.3390/molecules27206926

Configurationally stable dithia[7]helicene and dithia-quasi[8]circulene fused dithiolones.
M. Baudillon, T. Cauchy, N. Vanthuyne, N. Avarvari, F. Pop, Org. Chem. Front. 2022, 9, 4260–4270. 
https://doi.org/10.1039/D2QO00921H

Helical thienothiophene (TT) and benzothieno–benzothiophene (BTBT) derivatives: synthesis, structural characterization and semiconducting properties.
M. Mastropasqua Talamo, F. Pop, P. Hume, M. Abbas, G. Wantz, N. Avarvari, J. Mater. Chem. C. 2022, 10, 8034–8042. 
https://doi.org/10.1039/D2TC00861K

 2021

Old Donors for New Molecular Conductors: Combining TMTSF and BEDT-TTF with Anionic (TaF6)1−x/(PF6)x Alloys.
Magali Allain, Cécile Mézière, Pascale Auban-Senzier, Narcis Avarvari, Crystals MDPI 2021, 11 (4), pp.386
https://doi.org/10.3390/cryst11040386

Combined Experimental/Theoretical Study on the Luminescent Properties of Homoleptic/Heteroleptic Erbium(III) Anilate-Based 2D Coordination Polymers.
S. Ashoka Sahadevan, F. Manna, A. Abhervé, M. Oggianu, N. Monni, V. Mameli, D. Marongiu, F. Quochi, F. Gendron, B. Le Guennic, N. Avarvari, M. L. Mercuri, Inorg. Chem. 2021, 60, 17765-17774.    
https://doi.org/10.1021/acs.inorgchem.1c02386

Conducting chiral nickel(II) bis(dithiolene) complexes: structural and electron transport modulation with the charge and the number of stereogenic centres.
Abhervé, N. Mroweh, T. Cauchy, F. Pop, H. Cui, R. Kato, N. Vanthuyne, P. Alemany, E. Canadell, N. Avarvari, J. Mater. Chem. C. 2021, 9, 4119–4140. 
https://doi.org/10.1039/D1TC00439E

Chiroptical properties of anionic and neutral nickel(II) bis(dithiolene) complexes based on methyl and dimethyldddt ligands.
A. Abhervé, N. Mroweh, T. Cauchy, F. Pop, N. Vanthuyne, N. Avarvari, Chirality 2021, 34, 1–9. 
https://onlinelibrary.wiley.com/doi/10.1002/chir.23375

Schiff-base [4]helicene Zn(II) complexes as chiral emitters.
M. Savchuk, S. Vertueux, T. Cauchy, M. Loumaigne, F. Zinna, L. D. Bari, N. Zigon, N. Avarvari, Dalton Trans. 2021, 10533–10539.

Straightforward N-alkylation of diketopyrrolopyrroles through Mitsunobu reaction with benzyl, α-branched, and chiral alcohols.
M. Mastropasqua Talamo, F. Pop, N. Avarvari, Chem. Commun. 2021, 57, 6514–6517. 
https://doi.org/10.1039/D1CC02472H

Chiral Radical Cation Salts of Me-EDT-TTF and DM-EDT-TTF with Octahedral, Linear and Tetrahedral Monoanions.
N. Mroweh, A. Bogdan, F. Pop, P. Auban-Senzier, N. Vanthuyne, E. Lopes, M. Almeida, N. Avarvari, Magnetochemistry 2021, 7, 87. 
https://doi.org/10.3390/magnetochemistry7060087

Thiophene−Bipyridine Appended Diketopyrrolopyrrole Ligands and Platinum(II) Complexes.
Abhervé, M. Mastropasqua Talamo, S. Boi, V. Poupard, F. Gendron, B. Le Guennic, N. Avarvari, F. Pop, Inorg. Chem. 2021, 60, 7351–7363. 
https://doi.org/10.1021/acs.inorgchem.1c00534

Unusual stoichiometry, band structure and band filling in conducting enantiopure radical cation salts of TM-BEDT-TTF showing helical packing of the donors.
F. Pop, C. Mézière, M. Allain, P. Auban-Senzier, N. Tajima, D. Hirobe, H. M. Yamamoto, E. Canadell, N. Avarvari, J. Mater. Chem. C. 2021, 9, 10777–10786. 
https://doi.org/10.1039/D1TC01112J

Tuning the Organogelating and Spectroscopic Properties of a C3-Symmetric Pyrene-Based Gelator through Charge Transfer.
Gainar, T.-L. Lai, C. Oliveras-Gonzalez, F. Pop, M. Raynal, B. Isare, L. Bouteiller, M. Linares, D. Canevet, N. Avarvari, M. Sallé, Chem. Eur. J. 2021, 27, 2410 – 2420. 
https://doi.org/10.1002/chem.202003914

2020

In search of chiral molecular superconductors: κ-[(S,S)-DM-BEDT-TTF]2ClO4 revisited.
N. Mroweh, C. Mézière, F. Pop, P. Auban-Senzier, P. Alemany, E. Canadell, N. Avarvari, Adv. Mater. 2020, 32, 2002811. 
https://doi.org/10.1002/adma.202002811

Radical Cation Salts of Tetramethyltetrathiafulvalene (TM-TTF) and Tetramethylselenafulvalene (TM-TSF) with Chlorocyananilate-Based Anions.
S. Ashoka Sahadevan, A. Abhervé, N. Monni, P. Auban-Senziez, H. Cui, R. Kato, M. L. Mercuri, N. Avarvari, Cryst. Growth & Des. 2020, 20, 6777-6786.
https://dx.doi.org/10.1021/acs.cgd.0c00873

1,2,4,5-Tetrazine-based ligands and complexes.
O. Stetsiuk, A. Abhervé, N. Avarvari, Dalton Trans. 2020, 49, 5759-5777.
https://doi.org/10.1039/D0DT00827C

2019

Combining Chirality and Hydrogen Bonding in Methylated Ethylenedithio-Tetrathiafulvalene Primary Diamide Precursors and Radical Cation Salts.
N. Mroweh, F. Pop, C. Mézière, M. Allain, P. Auban-Senzier, N. Vanthuyne, P. Alemany, E. Canadell, N. Avarvari, Cryst. Growth Des. 2020, 20, 2516−2526. 
https://dx.doi.org/10.1021/acs.cgd.9b01665

Main-Group-Based Electro- and Photoactive Chiral Materials.
F. Pop, N. Zigon, N. Avarvari, Chem. Rev. 2019, 119, 8435−8478. 
https://doi.org/10.1021/acs.chemrev.8b00770

Heteroleptic NIR-Emitting YbIII/Anilate-Based Neutral Coordination Polymer Nanosheets for Solvent Sensing. 
S. Ashoka Sahadevan, N. Monni, M. Oggianu, A. Abhervé, D. Marongiu, M. Saba, A. Mura, G. Bongiovanni, V. Mameli, C. Cannas, N. Avarvari, F. Quochi, M. L. Mercuri, ACS Appl. Nano Mater. 2019, 3, 94-104.
https://doi.org/10.1021/acsanm.9b01740

Helicene Bis(pyrazol-1-yl)pyridine Ligands for Luminescent Transition-Metal Complexes.
A. Abhervé, K. Martin, A. Hauser, N. Avarvari, Eur. J. Inorg. Chem. 2019, 4807-4814.
https://doi.org/10.1002/ejic.201900870

Magnetic Molecular Conductors Based on Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) and the Tris(chlorocyananilato)ferrate(III) Complex. 
S. Ashoka Sahadevan, A. Abhervé, N. Monni, P. Auban-Senzier, J. Cano, F. Lloret, M. Julve, H. Cui, R. Kato, E. Canadell, M. L. Mercuri, N. Avarvari, Inorg. Chem. 2019, 58, 15359-15370.
https://doi.org/10.1021/acs.inorgchem.9b02404

Dysprosium Chlorocyananilate-Based 2D-Layered Coordination Polymers. 
S. Ashoka Sahadevan, N. Monni, A. Abhervé, G. Cosquer, M. Oggianu, G. Ennas, M. Yamashita, N. Avarvari, M. L. Mercuri, Inorg. Chem. 2019, 58, 13988-13998.
https://doi.org/10.1021/acs.inorgchem.9b01968

2018

Conformational Study and Chiroptical Properties of Chiral Dimethyl- Ethylenedithio Tetrathiafulvalene (DM-EDT-TTF).
T. Cauchy, F. Pop, J. Cuny, N. Avarvari, Chimia 2018, 72, 389–393. 
https://doi.org/10.2533/chimia.2018.389

Conducting Anilate-Based Mixed-Valence Fe(II)Fe(III) Coordination Polymer: Small-Polaron Hopping Model for Oxalate-Type Fe(II)Fe(III) 2D Networks. 
S. Ashoka Sahadevan, A. Abhervé, N. Monni, C. Sáenz de Pipaón, J.-R. Galán Mascarόs, J. C. Waerenborgh, B. J. C. Vieira, P. Auban-Senzier, S. Pillet, E.-E. Bendeif, P. Alemany, E. Canadell, M. L. Mercuri, N. Avarvari, J. Am. Chem. Soc. 2018, 140, 12611-12621.
https://doi.org/10.1021/jacs.8b08032

Nanosheets of Two-Dimensional Neutral Coordination Polymers Based on Near-Infrared-Emitting Lanthanides and a Chlorocyananilate Ligand.
S. Ashoka Sahadevan, N. Monni, A. Abhervé, D. Marongiu, V. Sarritzu, N. Sestu, M. Saba, A. Mura, G. Bongiovanni, C. Cannas, F. Quochi, N. Avarvari, M. L. Mercuri, Chem. Mater. 2018, 30, 6575-6586.
https://doi.org/10.1021/acs.chemmater.8b03399

Iron(II) and cobalt(II) complexes based on anionic phenanthroline-imidazolate ligands: reversible single-crystal-to-single-crystal transformations. 
A. Abhervé, S. Benmansour, C. J. Gómez-García, N. Avarvari, CrystEngComm 2018, 20, 4141-4150.
https://doi.org/10.1039/C8CE00561C

Structural Diversity in a New Series of Halogenated Quinolyl Salicylaldimides-Based FeIII Complexes Showing Solid-State Halogen-Bonding/Halogen···Halogen Interactions. 
S. Ashoka Sahadevan, E. Cadoni, N. Monni, C. Sáenz de Pipaón, J.-R. Galán Mascarόs, A. Abhervé, N. Avarvari, L. Marchiò, M. Arca, M. L. Mercuri, Cryst. Growth & Des. 2018, 18, 4187-4199.
https://doi.org/10.1021/acs.cgd.8b00753

Tetrathiafulvalene‐[2.2]paracyclophanes: Synthesis, crystal structures, and chiroptical properties.
C. Mézière, M. Allain, C. Oliveras‐Gonzalez, T. Cauchy, N.Vanthuyne, L. G. Sarbu, L. M. Birsa, F. Pop, N. Avarvari, Chirality 2018, 30, 568–575. 
https://onlinelibrary.wiley.com/doi/full/10.1002/chir.22831

2017

Synthesis and Physical Properties of Purely Organic BEDT-TTF-Based Conductors Containing Hetero/Homosubstituted Cl/CN-Anilate Derivatives.
S. Ashoka Sahadevan, N. Monni, A. Abhervé, P. Auban-Senzier, E. Canadell, M. L. Mercuri, N. Avarvari, Inorg. Chem. 2017, 56, 12564-12571. 
https://doi.org/10.1021/acs.inorgchem.7b01994